Ligand effects on the stereochemistry of Stille couplings, as manifested in reactions of Z-alkenyl halides.
نویسندگان
چکیده
Unexpected losses in stereochemistry from Stille reactions involving Z-alkenyl halides have been shown to be ligand dependent. A new set of reaction conditions has been developed that, in most cases, leads to highly stereoselective cross-couplings under mild conditions, along with improved yields.
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عنوان ژورنال:
- Chemical communications
دوره 48 69 شماره
صفحات -
تاریخ انتشار 2012